专利名称：Process for the catalytic oxidation of
aromatic compounds
发明人：Wolfgang A. Herrmann,Joao D. G.
Correia,Richard Fischer,WaldemarAdam,Jianhua Lin,Chantu R. Saha-Moller,Masao Shimizu
申请号：US08/378231申请日：19950125公开号：US05616734A公开日：19970401
摘要：The invention relates to the use of compounds of the formula I
R.sup.1.sub.a Re.sub.b O.sub.c (I),
where a is from 1 to 6, b is from 1 to 4 and c is from 1 to 14 and the sum of a, b and cis in accordance with the valence of from 5 to 7 of the rhenium, with the proviso that c isnot greater than 3·b, and where R.sup. 1 is identical or different and is an aliphatichydrocarbon radical having from 1 to 10 carbon atoms, an aromatic hydrocarbon radicalhaving from 6 to 10 carbon atoms or an arylalkyl radical having from 7 to 9 carbon atoms,with the radicals R.sup.1 being able, if desired, to be identically or differently substitutedindependently of one another and, in the case of &sgr;-bonded radicals, at least onehydrogen atom still being bonded to the carbon atom in the &agr; position, as catalystsfor the oxidation of electron-rich aromatic compounds and their derivatives and to aprocess for the oxidation of electron-rich aromatic compounds which comprises oxidizingelectron-rich C.sub.6 -C.sub.22 -aryl compounds and their derivatives in the presence of a
catalyst of the formula I and a peroxide-containing compound.
申请人：HOECHST AKTIENGESELLSCHAFT
代理机构：Curtis, Morris & Safford, P
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